Thursday, 26 March 2015

Thermal decomposition on Hadrian's Wall



We came across these limekilns on the north side of Hadrian's Wall near Housesteads. There was clearly a low ridge of limestone amongst the igneous intrusions. The used to dig out lumps of limestone and drop it into the kiln, having got a raging fire going at a temperature of over 1000 degrees Celsius. This is the reaction that took place.
The heat energy makes the calcium carbonate molecule fall apart to produce calcium oxide and carbon dioxide. It must be an endothermic reaction because we had to heat it up to get it to work.
Calcium oxide is a white powder that is often called quick lime. If added to water, it makes calcium hydroxide, which is often called slaked lime. Here's the reaction:
This is a very exothermic - it can give out a dangerous amount of heat energy. The calcium hydroxide is an alkali because of the OH- ions in it. OH- is called a HYDROXIDE ion.
The reason for doing all of this is that farmers can put the slaked lime alkali on their fields if the soil there is too acidic for growing crops. The calcium hydroxide can neutralise the acidic soils. The moorland soils in this part of the world are naturally acidic.